Rights Contact Login For More Details
- Wiley
More About This Title The Organometallic Chemistry of the Transition Metals, 7th Edition
English
- Includes end-of-chapter problems and their solutions
- Has up-to-date examples of fundamental reaction steps and emphasis on key topics like oxidation catalysis, CH functionalization, nanoclusters, and nanoparticles
- Adds coverage for ligand-assisted additions and eliminations, proton-coupled electron transfer, surface catalysis, green energy, and photoredox catalysis
English
Contents
Acknowledgment
List of Abbreviations
Periodic Table
1 Introduction
1.1 Why Study Organometallic Chemistry?
1.2 Coordination Chemistry
1.3 Werner Complexes
1.4 The Trans Effect
1.5 Soft versus Hard Ligands
1.6 The Crystal Field
1.7 The Ligand Field
1.8 Two Electron-Three Center Bonding
1.9 Four Electron-Three Center Bonding
1.10 Back Bonding
1.11 Trends in d Orbital Energies
1.12 Types of Ligand
References
Problems
2 Making Sense of Organometallics
2.1 The 18-Electron Rule
2.2 Limitations of the 18-Electron Rule
2.3 Electron Counting in Reactions
2.4 The Oxidation State Concept and its Limitations
2.5 Electroneutrality
2.6 Coordination Number and Geometry
2.7 Effects of Complexation
2.8 Differences between Metals
References
Problems
3 Alkyls and Hydrides
3.1 Alkyls and Aryls
3.2 Others-bonded Ligands
3.3 Metal Hydrides
3.4 Sigma Complexes
3.5 Bond Strengths
References
Problems
4 Ligand Substitution
4.1 Metal Carbonyls
4.2 Phosphines
4.3 N-Heterocyclic Carbenes
4.4 Dissociative Substitution
4.5 Associative Substitution
4.6 Redox Effects and Interchange Substitution
4.7 Photochemical Substitution
4.8 Counterions and Solvents in Substitution
References
Problems
5 Pi-Complexes
5.1 Alkene and Alkyne Complexes
5.2 Allyl Complexes
5.3 Diene Complexes
5.4 Cyclopentadienyl Complexes
5.5 Arenes and Other Alicyclic Ligands
5.6 Metalacycles
5.7 Stability of Polyene and Polyenyl Complexes
References
Problems
6 Oxidative Addition and Reductive Elimination
6.1 Introduction
6.2 Concerted Additions
6.3 SN2 Pathways
6.4 Radical Mechanisms
6.5 Ionic Mechanisms
6.6 Reductive Elimination
6.7 Sigma Bond Metathesis
6.8 Ligand-Assisted 12-Additions and Eliminations
6.9 Oxidative Coupling
6.10 Proton Coupled Electron Transfer
References
Problems
7 Insertion and Elimination
7.1 Introduction
7.2 11-Insertion
7.3 12-Insertion
7.4 Outer Sphere Insertions
7.5 a b g and d Elimination
References
Problems
8 Addition and Abstraction
8.1 Introduction
8.2 Nucleophilic Addition to CO
8.3 Nucleophilic Addition to Polyene and Polyenyls
8.4 Nucleophilic Abstraction
8.5 Electrophilic Addition and Abstraction
8.6 Single-Electron Transfer and Radical Reactions
References
Problems
9 Homogeneous Catalysis
9.1 Catalytic Cycles
9.2 Alkene Isomerization
9.3 Hydrogenation
9.4 Alkene Hydroformylation
9.5 Alkene Hydrocyanation
9.6 Alkene Hydrosilylation
9.7 Coupling Reactions
9.8 Organometallic Oxidation Catalysis
9.9 Electrocatalysis
9.10 Photoredox Catalysis
9.11 Surface Supported Single Atom and Cooperative Catalysis
References
Problems
10 Physical Methods
10.1 Mechanism
10.2 H NMR Spectroscopy
10.3 C NMR Spectroscopy
10.4 P NMR Spectroscopy
10.5 Dynamic NMR
10.6 Spin Saturation Transfer
10.7 T1 and the Nuclear Overhauser Effect
10.8 IR Spectroscopy
10.9 Crystallography
10.10 Electrochemistry and EPR
10.11 Computation
10.12 Other Methods
References
Problems
11 M-L Multiple Bonds
11.1 Carbenes
11.2 Carbynes
11.3 Bridging Carbenes and Carbynes
11.4 N-Heterocyclic Carbenes
11.5 Multiple Bonds to Heteroatoms
References
Problems
12 Metathesis Polymerization and Bond Activation
12.1 Alkene Metathesis
12.2 Alkene Dimerization Oligomerization and Polymerization
12.3 Activation of CO and CO2
12.4 C-H Activation
12.5 Dehydrogenative Oxidation and Hydrogen Borrowing
References
Problems
13 Green Energy & Materials Applications
13.1 Green Chemistry
13.2 Energy Chemistry
13.3 Clusters and Nanoparticles
13.4 Organometallic Materials
References
Problems
14 Organic Applications
14.1 Carbon-Carbon and Carbon-Heteroatom Coupling
14.2 Metathesis
14.3 Cyclopropanation and C–H Insertion
14.4 Hydrogenation
14.5 Carbonylation
14.6 Oxidation
14.7 C-H Activation
14.8 Click Chemistry and Cycloaddition
14.9 Photoredox Catalysis
References
Problems
15 Paramagnetic and High-Oxidation-State Complexes
15.1 Magnetism and Spin States
15.2 Cyclopentadienyl Complexes
15.3 f-Block Complexes
References
Problems
16 Bioorganometallic Chemistry
16.1 Introduction
16.2 Coenzyme B12
16.3 Nitrogen Fixation
16.4 Nickel Enzymes
16.5 Artificial Enzymes
16.6 Biomedical and Biocatalytic Applications
References
Problems
Useful Texts on Allied Topics
Major Reaction Types
Solutions to Problems
Index 000
